I wouldn't do the ACV before a PT. the purpose of ACV is to reseal and close the cuticle. The point of the PT is to absorb into the hair.
ACV needs to be very diluted with water to keep the pH from being too acidic.

3a/f/iii
Modified CG since 11/5/11
CLEANSE: VO5 Vanilla Mint Tea Clarifying, DevaCare No-Poo, CHS Treatment Shampoo
RO: DevaCare One Condition, SS Caitlin's Conditioner, Mop Top Daily Conditioner
LI: SS Repairing Protein Treatment, CHS Silk Leave-In
STYLE: Re:Coil, Curl Keeper, Deva Ultra Defining Gel, Curls Rock Amplifier and Strong Hold Mousse, Sweet Curls Elixirs Okra Gel and Hard Hold Gel, SS Curl Enhancing Jelly and Firm Hold Gel