at the risk of sounding silly, which clarifying shampoos? If you have hard water, and they contain a form of soap, castille or whatever, you're not clarifying, you're making it worse. Soap bars will make it worse. Anything with a soap type product. You need to use something with a chemical surfactant rather than a soap. Most "natural" shampoos are made out of liquid soap.

However, if its a detergent and its got citric acid in it, then I don't know what else to tell you. Sorry
Grand Goobah Caedran, Aqueous Infusion of Demulcents, Order of the Curly Crusaders

Fia 2cFi, fine texture, med porosity CG 5-29-09 * My hair loves protein! Currently using : DermOrganics Shampoo and IHM, G2B Kinkier Mousse, Re:Coil VMM, Anything Spiral Solutions! MO Sealing. Coconut Oil Pre-Poo, once a month Hard Water shampoo. Avoiding Glycerin in finishing products.