Sure, in between shampoos would probably work well. ACV can be drying though, so watch your hair. I know of a few who use it every time they cleanse, others, like me, who do weekly ones, and others whose hair /scalp hate ACV.
CG since 11/2011
2c /3a F /Mii, low porosity

Go To Products /Routine:
Clarifying: Suave Essentials Strawberry
Low Poo: Renpure Luxurious Argan Oil
CO: Suave Essentials Strawberry, V05 Kiwi Lime
RO /LI: Tresemme Perfectly (un)Done, Cure Care, V05 Kiwi Lime Squeeze, Suave Essentials Strawberry, Renpure Brazilian Keratin (old formula)
Stylers: LALSG, AIF, HETT, Suave Professionals Firm Control
PT: IAGirl's as needed