Should I wash my hair before treating my flaky scalp?

I have noticed my scalp is flaking a lot. It comes up in big patches with flaky edges which break down into big and small flakes. I have braids in, so it's not as easy to take them out.The treatments I've thought about are; spraying my scalp with water/tea tree oil mix.And Apple Cider Vinegar rinse.Should I wash my hair before I do this? I find that the treatments make my hair itch more when I apply it to dirty hair.

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