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propylene glycol in a bottle

An ingredient found in many personal-care products like shampoo, hair conditioner, and styling product, propylene glycol is widely used because of its relatively low cost and versatile nature. Its inclusion in a formula can fulfill a variety of purposes, which makes it a popular choice by the cosmetics chemist. However, some manufacturers have recently made the decision to no longer include propylene glycol in their products.

Do not be alarmed by the term antifreeze or by the chemical, propylene glycol. It is safe at the low concentrations when used in personal care products.

This is possibly due to misinformation and propaganda circulated on the Internet in the interest of marketing "natural" products. I am an avid supporter of using natural products, avoiding putting toxins into our bodies whenever possible or practical. I get frustrated by the dissemination of inaccurate and incomplete information in an attempt to frighten consumers into using different products. In this article, I seek to clear up some misconceptions about this chemical.

The chemical facts about propylene glycol

  • It is water-soluble.
  • It is synthetic.
  • It is non-toxic.
  • It is easily metabolized. 

Propylene glycol (also known as 1,2 propanediol) is a relatively small molecule with two alcohol (hydroxyl) groups (-OH). It is a colorless, odorless liquid that is completely water-soluble. PG is a synthetic product obtained from the hydration of propylene oxide, which is derived from petroleum products. I do not personally consider a petroleum-sourced product to be a bad thing, as I consider the final structure and its properties to be more relevant than the source (unless contamination is a concern).

The FDA has categorized propylene glycol as "Generally Recognized as Safe."

Even with prolonged direct exposure, there is little to no skin irritation or sensitization. It subsides quickly once the area is flushed. The MSDS recommends avoiding direct handling due to potential irritation, which is a smart recommendation for any chemical--this is not an indication of the level of toxicity. Remember: in the chemical industry when a worker is exposed to continuous and large quantities of a chemical in its concentrated form, it is imperative to use the strongest safety precautions possible. This is not relevant to consumers using a product by the teaspoonful, if that.

Propylene glycol is non-toxic when ingested, even in reasonably large amounts.

Unlike its dangerous and frequently lethal cousin, ethylene glycol, PG is easily metabolized by the liver into normal products of the citric acid metabolic cycle, which are completely nontoxic to the body. Approximately 45 percent of any ingested PG is excreted directly from the body and never even comes into contact with the liver. The elimination half-life for propylene glycol is approximately four hours, and there is no bioaccumulation (buildup in the body over time). A few rare incidents have occurred where a person ingested a large quantity of propylene glycol and suffered some liver and neurological effects as a result, but these were short-lived and subsided once the material was metabolized and excreted.

molecular structure

The metabolic cycle for propylene glycol

  • Propylene glycol → lactic acid → pyruvic acid → CO2 + water

Both experimental and anecdotal evidence to date indicate PG to be completely non-carcinogenic, despite its "petroleum-based" origin. In an interesting study, some rats were fed propylene glycol at amounts equal to 5% of all of their food intake every day for two years, which is a pretty huge volume over a large portion of their lifetime. There were no observable effects on their health or behavior.

What "antifreeze" really means for consumers

The word is frequently used to alarm consumers, and is simply a scientific term used to describe the lowering or depression of the freezing point of a liquid. An example is the application of salt to roads and walkways in a snowstorm. This process helps melt snow and ice and prevent development of dangerous icy conditions. The salt accomplishes this by lowering the freezing point of water. This is an example of a "safe" chemical being used as antifreeze. Do not be alarmed by the term antifreeze or by the chemical, propylene glycol. While few chemicals are entirely without risk, propylene glycol is considered to be safe at the low concentrations, used in personal care products and even food products.

Propylene glycol in personal care products

  • It is an effective humectant.
  • It is a solvent for fragrances and preservatives.
  • It can be used as an emulsifier or co-surfactant.
  • It is used as a solvent for pigments in cosmetics.
  • It can be used as a preservative due to its antifungal and antimicrobial properties.
  • It is frequently used in deodorants and antiperspirants.
  • It is found in hand cleansers and disinfecting gels.
  • It is a common additive in shaving creams and gels.

I think for those of us with curly hair, propylene glycol's main benefit is the fact that it is a humectant, and a pretty effective one at that.

How propylene glycol affects hair

  • It applies like a humectant (attracts water to the hair).
  • It won't cause build-up. 
  • It will not evaporate easily (which may cause dry hair).

The application of propylene glycol that is most relevant to those of us with curly hair is as a humectant. All the usual cautions apply with regard to its capabilities to attract water to the hair from the environment or to draw water from the hair to itself. Unless you have the perfect atmospheric conditions, you may experience problems with this ingredient.

Propylene glycol is a completely water-soluble material that will not build up on the hair. It is also important to note that it is a diol with low volatility, meaning it will not evaporate easily and cause dry hair in the manner of low molecular weight alcohols such as SD alcohol and isopropyl alcohol.

Curl Chemist's conclusion: Don't fear propylene glycol

Propylene glycol should not be a feared ingredient. If product manufacturers are finding replacement ingredients to fulfill the same purposes in their formulas served by propylene glycol, I see no harm in that. However, I hesitate to support marketing materials that use this as a selling point.

As a curly, it would be wise to be aware if you are using products that contain this ingredient, just in case you observe increased frizz or dryness. Use plenty of moisturizing products to help lock moisture into your hair shaft, which can help prevent any potential problems caused by a humectant.


Writer Tonya McKay Becker is a curly-haired polymer scientist and cosmetic chemist whose academic and industrial research experience have provided her with expertise in the fundamentals and applications of polymer science and colloid chemistry. 

References

"Case Studies in Environmental Medicine (CSEM), Ethylene Glycol and Propylene Glycol Toxicity" 

What is Propylene Glycol?

Gaunt, IF, Carpanini, FMB, Grasso, P and Lansdown, ABG, "Long-term toxicity of propylene glycol in rats, Food and Cosmetics Toxicology," April 1972, 10(2), pages 151-162. Dow

McKay, T. "Humidity, Humectants and Hair", online publication, Aug. 2007

0 Comments
As a holistic health practitioner,swimming in a sea of neutricueticals,and topically applied preps,Youv've answered a few of my concerneds, that have come up with otherdoctors, and health professionals I work with.I'm armed with the curly girl network chemist.Youre awesome, glad I found you. Michele Beck HHP, Del Mar, CA.
Thank you, thank you, thank you! I was just about to start a thread asking what PG does for hair.

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